Suggestions by @timjeromy12

J.K. Simmons

as J Jonah Jameson in Spider-Man 3 (2007)

Doug Jones

as Chameleon in Spider-Man 3 (2007)

Timothy Olyphant

as Scorpion in Spider-Man 3 (2007)

Steve Austin

as Rhino in Spider-Man 3 (2007)

Matthew Lillard

as Cletus Kassady in Spider-Man 3 (2007)

Eliza Dushku

as Black Cat (Felicia Hardy) in Spider-Man 3 (2007)

Ben Kingsley

as Vulture in Spider-Man 3 (2007)

Nicolas Cage

as Ghost Rider in Spider-Man 3 (2007)

Thomas Haden Church

as Sandman in Spider-Man 3 (2007)

Topher Grace

as Venom in Spider-Man 3 (2007)

Eminem

as Spider-Man Rapper in Spider-Man 3 (2007)

Michael Clarke Duncan

as Kingpin in Spider-Man 3 (2007)

Ben Affleck

as Daredevil in Spider-Man 3 (2007)

Elya Baskin

as Mr Ditkovitch in Spider-Man 3 (2007)

Kirsten Dunst

as Mary Jane Watson in Spider-Man 3 (2007)

Bryce Dallas Howard

as Gwen Stacy in Spider-Man 3 (2007)

James Franco

as Harry Osborn in Spider-Man 3 (2007)

Tobey Maguire

as Spider-Man in Spider-Man 3 (2007)

Hugh Jackman

as Wolverine in Avengers Confidential: Black Widow and Punshier (2000's)

Tobey Maguire

as Spider-Man in Avengers Confidential: Black Widow and Punshier (2000's)