Suggestions by @superbat

Gorillaz

as Soundtrack Music in Spider-Man (Season 2) (2002-2003)

Al Pacino

as Silvio Manfredi in Spider-Man (Season 2) (2002-2003)

Kevin Grevioux

as Tombstone in Spider-Man (Season 2) (2002-2003)

George Clooney

as Tony Stark in Spider-Man (Season 1) (2001-2002)

James Marsden

as Matt Murdock in Spider-Man (Season 2) (2002-2003)

Arnold Vosloo

as Mac Gargan in Spider-Man (Season 2) (2002-2003)

Ralph Fiennes

as Dmitri Smerdyakov in Spider-Man (Season 2) (2002-2003)

Mark Hamill

as Otto Octavius in Spider-Man (Season 2) (2002-2003)

Michael Rosenbaum

as Max Dillon in Spider-Man (Season 2) (2002-2003)

Linkin Park

as Soundtrack Music in Spider-Man (Season 2) (2002-2003)

Hoobastank

as Soundtrack Music in Spider-Man (Season 2) (2002-2003)

Sarah Michelle Gellar

as Sally Avril in Spider-Man (Season 2) (2002-2003)

Mark Harmon

as Captain George Stacy in Spider-Man (Season 2) (2002-2003)

Hayden Christensen

as Harry Osborn in Spider-Man (Season 2) (2002-2003)

Joseph Gordon-Levitt

as Peter Parker in Spider-Man (Season 2) (2002-2003)

Avril Lavigne

as Soundtrack Music in Spider-Man (Season 2) (2002-2003)

Coldplay

as Soundtrack Music in Spider-Man (Season 2) (2002-2003)

Sum 41

as Soundtrack Music in Spider-Man (Season 2) (2002-2003)

Matt Schulze

as Logan Howlett in The X-Men (1999)

Ben Kingsley

as Charles Xavier in The X-Men (1999)