Suggestions by @superbat

Edward Norton

as Hank Pym in Spider-Man (Season 4) (2004-2005)

Robert Sean Leonard

as Hank Pym in Spider-Man (Season 4) (2004-2005)

Nathan Fillion

as Clint Barton in Spider-Man (Season 4) (2004-2005)

Kate Beckinsale

as Natasha Romanoff in Spider-Man (Season 4) (2004-2005)

Billy Crudup

as Bruce Banner in Spider-Man (Season 4) (2004-2005)

Nikolaj Coster-Waldau

as Thor Odinson in Spider-Man (Season 4) (2004-2005)

George Clooney

as Tony Stark in Spider-Man (Season 4) (2004-2005)

Matt Damon

as Steve Rogers in Spider-Man (Season 4) (2004-2005)

Kurt Russell

as Nick Fury in Spider-Man (Season 4) (2004-2005)

David Harbour

as Morris Bench in Spider-Man (Season 4) (2004-2005)

Kevin Durand

as Aleksei Sytsevich in Spider-Man (Season 4) (2004-2005)

Jonathan Banks

as Adrian Toomes in Spider-Man (Season 4) (2004-2005)

Russell Crowe

as Sergei Kravinoff in Spider-Man (Season 4) (2004-2005)

Ralph Fiennes

as Dmitri Smerdyakov in Spider-Man (Season 4) (2004-2005)

Metallica

as Soundtrack Music in Spider-Man (Season 4) (2004-2005)

Skeet Ulrich

as Herman Schutlz in Spider-Man (Season 4) (2004-2005)

Ray Liotta

as Joseph Martello in Spider-Man (Season 4) (2004-2005)

Cole Hauser

as Benjamin Poindexter in Spider-Man (Season 4) (2004-2005)

Sean Astin

as Foogy Nelson in Spider-Man (Season 4) (2004-2005)

Bryan Cranston

as Ben Urich in Spider-Man (Season 4) (2004-2005)