Suggestions by @paulcoolman

Spoiler

as *Sinister Laugh* in Batman Begins (2005)

Aaron Eckhart

as Harvey Dent in Batman Begins (2005)

Tom Wilkinson

as Carmine Falcone in Batman Begins (2005)

Rutger Hauer

as William Earle in Batman Begins (2005)

Morgan Freeman

as Lucius Fox in Batman Begins (2005)

Ken Watanabe

as Ra's Al Ghul in Batman Begins (2005)

Gary Oldman

as Sgt. James Gordon in Batman Begins (2005)

Cillian Murphy

as Scarecrow in Batman Begins (2005)

Amy Adams

as Rachel Dawes in Batman Begins (2005)

Michael Caine

as Alfred Pennyworth in Batman Begins (2005)

Christian Bale

as Batman in Batman Begins (2005)

Chris Evans

as Superman in Identity Crisis

Jeff Bridges

as Andy Barber in Defending Jacob (1990)

Pedro Pascal

as Frank Woods in Call of Duty: Black Ops

Kenneth Branagh

as Sanders in The Man From UNCLE (2015)

Joseph Kosinski

as Director in The Man From UNCLE (2015)

Vanessa Kirby

as Victoria Vinciguerra in The Man From UNCLE (2015)

Hugh Laurie

as Alexander Waverly in The Man From UNCLE (2015)

Gemma Arterton

as Gaby Teller in The Man From UNCLE (2015)

Robert Pattinson

as Illya Kuryakin in The Man From UNCLE (2015)