Suggestions by @nurali

Alfred Molina

as Dr. Otto Octavius/Doctor Octopus in Spider-Man 2 (2004/Deleted Scenes/Alternate Versions)

James Franco

as Harry Osborn in Spider-Man 2 (2004/Deleted Scenes/Alternate Versions)

Kirsten Dunst

as Mary Jane Watson in Spider-Man 2 (2004/Deleted Scenes/Alternate Versions)

Hugh Jackman

as Logan/Wolverine in Spider-Man 2 (2004/Deleted Scenes/Alternate Versions)

Tobey Maguire

as Peter Parker/Spider-Man in Spider-Man 2 (2004/Deleted Scenes/Alternate Versions)

Bruce Campbell

as Quentin Beck/Mysterio in Spider-Man (2002/Deleted Scenes/Alternate Versions)

Robert Knepper

as Cletus Kasady/Carnage in Spider-Man (2002/Deleted Scenes/Alternate Versions)

Benicio del Toro

as Dr. Michael Alexander Morbius/Morbius the Living Vampire in Spider-Man (2002/Deleted Scenes/Alternate Versions)

Gerard Butler

as Sergei Kravinoff/Kraven the Hunter in Spider-Man (2002/Deleted Scenes/Alternate Versions)

Dylan Baker

as Dr. Curtis "Curt" Connors/The Lizard in Spider-Man (2002/Deleted Scenes/Alternate Versions)

Cliff Robertson

as Uncle Ben Parker in Spider-Man (2002/Deleted Scenes/Alternate Versions)

James Franco

as Harry Osborn in Spider-Man (2002/Deleted Scenes/Alternate Versions)

Cameron Dallas

as Kelsey Winslow in Power Rangers: Gender Swap

Inon Zur

as Composer 4 in The Amazing Spider-Man Duology - (Webb Cut)

Matt Letscher

as Hobgoblin in Sam Raimi's Marvel Cinematic Universe

Robert Knepper

as Carnage in Sam Raimi's Marvel Cinematic Universe

Chad Kroeger

as Composer #3 in Spider-Man (2002) - Extended Cut

Ewan McGregor

as Carnage in Spider-Man: Friend or Foe (Live action video game/movie)

Timothy Olyphant

as Mac Gargan in Spider-Man TAS (Live Action)

Richard Harmon

as TASM Carnage in Spiderman Villain Counterparts