When the hero of the show and one of the antagonists have a romantic tone right out in the open, as opposed to Foe Romance Subtext. This adds a degree of tension to the relationship, and as long as you make sure the antagonist is less of a "villain", we're allowed to root for them. As the name indicates, this tends to be the gender dynamic of a male hero and a female villain. A female hero and a male villain is far rarer, but not unheard of.
Fan Casting
Catwoman
Batman
Black Cat
Spider-Man (Peter Parker)
Jon Snow
Rose/Huntsgirl
Talia al Ghul
Ygritte
Phoebe Halliwell
Arno Dorian
Élise de la Serre
Maria Thorpe
Altaïr Ibn-La'Ahad
Commander Shepard
Jake Long
Catra
Daredevil
Elektra
Rey Skywalker
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